Document Type : Original Research Article
Authors
- Sharareh Ravanshad
- Hakimeh Asvar
- Fatemeh Fouladi
- Arezoo Pourkazemi
- Maasoomeh Shamsizadeh
- Maryam Khalili
- Maria Merajoddin
- Abdolkarim Zare
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
Abstract
In this work, N,N,N',N'-tetramethylethylene-diaminium-N,N'-disulfonic acid chloride {[TMEDSA][Cl]2} has been utilized as a highly effective catalyst in order to promote the following organic transformations under green, solvent-free and mild conditions: (i) the synthesis of 4H-pyrano[2, 3-c]pyrazoles from aromatic aldehydes, 3-methyl-1-phenyl-2-pyrazolin-5-one and malononitrile, (ii) the preparation of α-carbamatoalkyl-β-naphthols from arylaldehydes, β-naphthol and alkyl carbamates, and (iii) the production of α-amidoalkyl-β-naphthols from arylaldehydes, β-naphthol and amides.
Graphical Abstract
![N,N,N',N'-tetramethylethylene-diaminium-N,N'-disulfonic acid chloride as a highly effective catalyst for the synthesis of 4H-pyrano[2, 3-c]pyrazoles, α-carbamatoalkyl-β-naphthols and α-amidoalkyl-β-naphthols](javascript:loadModal('N,N,N',N'-tetramethylethylene-diaminium-N,N'-disul ... ', 'data/ajgc/coversheet/471558159911.jpg'))
Keywords
- N
- N'
- N'-Tetramethylethylene-diaminium-N
- N'-disulfonic acid chloride {[TMEDSA][Cl]2} Sulfonic acid-functionalized ionic liquid 4H-Pyrano[2
- 3-c]pyrazole α-Carbamatoalkyl-β-naphthol α-Amidoalkyl-β-naphthol
Main Subjects
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