Application of nano-CeO2 catalyst as a suitable and useful catalyst in the synthesis of 1,8-dioxooctahydroxanthenes

Baghernejad, Bita; Ghapanvari, Hamed

doi:10.22034/ajgc.2021.281471.1301

Document Type : Original Research Article

Authors

Department of Chemistry, School of Sciences, Payame Noor University (PNU), 19395-3697, Iran

https://doi.org/10.22034/ajgc.2021.281471.1301

Abstract

Xanthene and their derivatives are an important class of broad-spectrum heterocyclic compounds used as fluorescent dyes to visualize biomolecules and lasers. They have been reported to be antiviral for photodynamic treatment, bactericidal activity in agriculture. In this research, a simple method for the synthesis of high-efficiency 1,8-dioxooctahydroxanthenes through the reaction from aromatic aldehyde and dimedon derivatives in the presence of nano-CeO₂ catalyst in water under the reflux conditions. The results revealed that this synthetic reaction is very simple and 1,8-dioxooctahydroxanthene derivatives produced with good yields compared to other articles. The advantages of this method include catalyst recovery, high efficiency and easy operation method. As shown in Table 5, the highest efficiency (95%) in a short time (1 h) was obtained in this study, which is very important compared to other previous methods presented.

Graphical Abstract

Keywords

Main Subjects

Organic Chemistry

References

[1]. Banerjee A., Mukherjee A.K. Stain Technol.,1981, 56:83

[2]. Hideu T. Chemical Abstract, 1981, 95:80922b

[3]. Carreon J.R., Roberts M.A., Wittenhagen L.M., Kelley S.O. Org Lett., 2005, 7:99

[4]. Poupelin J.P., Saint-Ruf G., Foussard-Blanpin O., Narcisse G., Uchida-Ernouf G., Lacroix R. Eur. J. Med. Chem., 1978, 13:67

[5]. Lamberk R.W., Martin J.A., Merrett J.H., Parkes K.E.B., Thomas G.J. PCT Int. Appl. WO9706178, 1997. Chemical Abstract, 1997, 126:212377y

[6]. Wang J.Q., Harvey R.G. Tetrahedron, 2002, 58:5927

[7]. Knight D.W., Little P.B. J. Chem. Soc. Perkin Trans., 2001, 14:1771

[8]. Casiraghi G., Casnati G., Cornia M. Tetrahedron Lett., 1973, 14:679

[9]. Jin T.S., Zhang J.S., Xio J.C., Wang A.Q., Li T.S. Synlett.,2004, 5:866

[10]. Baghernejad B., Rostami Harzevili M. Chem. Methodolog., 2020, 5:90

[11]. Mohamadpour F., Feilizadeh M. Chem. Methodolog., 2020, 4:647

[12]. Gaikwad S.V., Gaikwad, Lokhande P.D. J. Appl. Organomet. Chem., 2021, 1:1

[13]. Hote B.S., Muley D.B., Mandawad G.G. J. Appl. Organomet. Chem., 2021, 1:9

[14]. Baghernejad B. J. Appl. Organomet. Chem., 2021, 1:17

[15]. Jin T.S., Zhang J.S., Wang A.Q., Li T.S. Ultrason. Sonochem., 2006, 13:220

[16]. John A., Yadav P.J.P., Palaniappan S. J. Mol. Catal. A: Chem.,2006, 248:121

[17]. Khosropour A.R., Khodaei M.M., Moghannian H. Synlett., 2005, 6:955

[18]. Das B., Thirupathi P., Reddy K.R., Ravikanth B., Nagarapu L. Catal. Commun., 2006, 7:737

[19]. Muthuchudarkodi R.R., Kalaiarasi S. J. Scienc. Research., 2016, 5:543

[20]. Horning E.C., Horing M.G. J. Org. Chem.,1946,11:95

[21]. Lande M.P., Gadekar T., Pawar G., Magar R. Bull. Chem. React. Eng. Catal., 2018, 3:436

[22]. Babadoust Sh. Int. J. Chem. Biochem. Sci., 2014, 6:72

[23]. Darviche F., Balalaie S., Chadegani F., Salehi P. Synth. Commun., 2007, 37:1059

[24]. Deshmukh S., Kadam K., Shisodia M.V. Int. J. Chem. Phys. Scienc., 2018, 7:75

[25]. Noori Sadeh F., Fatahpour M., Hazeri N., Taher Maghsoodlou M., Lashkari M. Acta. Chem. Isaci., 2017, 4:25

Asian Journal of Green Chemistry

Application of nano-CeO2 catalyst as a suitable and useful catalyst in the synthesis of 1,8-dioxooctahydroxanthenes

References

References

Volume 5, Issue 3
July 2021
Pages 271-277

Application of nano-CeO2 catalyst as a suitable and useful catalyst in the synthesis of 1,8-dioxooctahydroxanthenes

References

References

Volume 5, Issue 3July 2021Pages 271-277

Volume 5, Issue 3
July 2021
Pages 271-277