Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
A new application of nickel nanoparticles as a heterogeneous catalyst for synthesis of 1-amidoalkyl-2-naphthols according to green chemistry principles
134
141
EN
Fatemeh
Hakimi
0000-0002-4580-4139
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
fatemeh.hakimi@yahoo.com
Fatemeh Sadat
Oreyzi
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
n_oreizy@yahoo.com
Fatemeh
Bani Fatemeh
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
Elham
Golrasan
0000-0003-0853-0033
Department of Chemistry, Payame Noor University, Tehran, P.O. Box 19395-4697, Iran
egolrasan@yahoo.com
10.22034/AJGC/2020.2.1
1-amidoalkyl-2-naphthols were prepared <em>via</em> one-pot multi-component reaction of 2-naphthol, aldehydes, and amides in the presence of nickel nanoparticles as a solid phase acidic catalyst, under solvent-free condition at 100 °C. The recent literature survey reveals that the nano nickel was used as heterogeneous catalyst and received noteworthy attention because of its inexpensive, non-toxic, low corrosion, waste minimization, easy transport and disposal of the catalyst. Short reaction times, high yields, and easy work-up are the advantages of this protocol.
Nickel nanoparticles,1-amidoalkyl-2-naphthol,Green chemistry,Multicomponent reaction
https://www.ajgreenchem.com/article_85885.html
https://www.ajgreenchem.com/article_85885_e0242acb80acec8852a1f037ee3d6553.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Green synthesis of new hippuric hydrazones
142
148
EN
Harith M.
Al-Ajely
Department of Chemistry, College of Science, University of Mosul, Mosul, Iraq
harith_mahammed@yahoo.com
10.22034/AJGC/2020.2.2
Hippuric hydrazones <strong>4–8</strong> were prepared starting from treating the corresponding acid with ethanolic HCl forming the corresponding ester <strong>2</strong>. The formed ester was then converted to ethyl hippurate <strong>3</strong> by treating the ester with hydrazine hydrate. The formed ethyl hippurate was then irradiated with various substituted aromatic aldehydes under solvent-free conditions forming new series of hippuric hydrazones <strong>4–8</strong>. Developing clean synthetic route for synthesizing hippuric hydrazones is the main point of this work which is environmentally and economically desirable. The synthesized compounds were confirmed by spectral NMR, mass, IR and CHN analysis data.
hydrazone,Solvent free conditions,Microwave
https://www.ajgreenchem.com/article_87037.html
https://www.ajgreenchem.com/article_87037_3f3cea038a239bba315df1f6491af48b.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Electrochemical behaviour of 5-methoxy-5,6-bis(3-nitropheyl-4,5-dihydro-1,2,4-triazine-3(2H))-thione in presence of salicylaldehyde on zinc cathode with surface morphology and biological activity
149
158
EN
Sasigolli Annappa
Srikanta
Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, India
shreekanta.camistry@gmail.com
Putta Naik
Parmeswara Naik
Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, India
parashchem@gmail.com
Ganga naik
Krishanamurthy
Department of Chemistry, Sahyadri Science College, Shivamogga, Karnataka, India
gkmnaiksahyadri@gmail.com
10.22034/AJGC/2020.2.3
This paper presents an innovative, green and organic electro synthesis in order to prepare Schiff base product by the reduction of 5-methoxy-5,6-bis (3-nitropheyl-4,5-dihydro-1,2,4-triazine-3(2<em>H</em>))-thione followed by the condensation on zinc cathode in aqueous alkaline ethanol media in the presence of salicylaldehyde at room temperature. The main characteristic of this proposal is the electro-reduction and electro-condensation. The bulk electrolysis at constant potential was performed in a three-electrode undivided cell in order to prepare Schiff base. In this sense, good yields and easy purification were achieved. Results indicate that thereduction produced high current in the cell and succeeded a green chemistry process. Products were characterized by IR, NMR (<sup>1</sup>H, <sup>13</sup>C), and SEM.
Electrolysis,Surface morphology,Organic electro-synthesis,cathode
https://www.ajgreenchem.com/article_87468.html
https://www.ajgreenchem.com/article_87468_3bf666c4e932b04166302ef31015ef88.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
A green synthesis of isoquinolines using Ru(II)/peg-400 as homogeneous recyclable catalyst via C-H/N-N bond activation
159
172
EN
Shrinivas L.
Nakkalwar
Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India
snakkalwar@rediffmail.com
Hanmant M.
Kasralikar
Department of Chemistry, Shri Muktanand Mahavidyalaya, Gangapur,Dist. Aurangabad MS, India
kasralikerhm1979@gmail.com
Nitish S.
Kaminwar
Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India
nskaminwar@gmail.com
Shivaji B.
Patwari
Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India
sbpatwari67@gmail.com
Vivekanand B.
Jadhav
Department of Chemistry, L. B. S. Mahavidyalaya, Dharmabad, Dist. Nanded, MS, India
viveka22@gmail.com
10.22034/AJGC/2020.2.4
A novel and green synthesis of 1-phenyl isoquinoline derivatives has been developed using [Ru(<em>p-</em>cymene)Cl<sub>2</sub>]<sub>2</sub>, as a homogeneous recyclable catalyst, with Cu(OAc)<sub>2</sub> and AgSbF<sub>6</sub> as oxidant and additive respectively, in PEG-400 biodegradable and green solvent <em>via</em> C-H/N-N functionalization of 1-(diphenylmethylene) hydrazine and aryl substituted acetylene. This protocol gives a simple extraction procedure, biodegradable and green solvent, high atom economy, reusable catalytic system and wide substrate scope with high yield of the product for the synthesis of isoquinoline derivatives.
Ru(II)/PEG-400,Green synthesis,Homogeneous catalyst,Biodegradable solvent
https://www.ajgreenchem.com/article_87603.html
https://www.ajgreenchem.com/article_87603_656b9322a0876d2425ababb7911a891d.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
N,N,N',N'-tetramethylethylene-diaminium-N,N'-disulfonic acid chloride as a highly effective catalyst for the synthesis of 4H-pyrano[2, 3-c]pyrazoles, α-carbamatoalkyl-β-naphthols and α-amidoalkyl-β-naphthols
173
182
EN
Sharareh
Ravanshad
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
sharareh.ravanshad@gmail.com
Hakimeh
Asvar
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
h.asvar@chmail.ir
Fatemeh
Fouladi
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
fatima.fouladiiii@gmail.com
Arezoo
Pourkazemi
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
a.pourkazemi@yahoo.com
Maasoomeh
Shamsizadeh
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
masoumehshamsizadeh@gmail.com
Maryam
Khalili
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
m.khalili9099@yahoo.com
Maria
Merajoddin
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
maria.merajoddin@yahoo.com
Abdolkarim
Zare
Department of Chemistry, Payame Noor University, PO Box 19395-3697 Tehran, Iran
abdolkarimzare@yahoo.com
10.22034/AJGC/2020.2.5
In this work, <em>N</em>,<em>N</em>,<em>N'</em>,<em>N'</em>-tetramethylethylene-diaminium-<em>N</em>,<em>N</em>'-disulfonic acid chloride {[TMEDSA][Cl]<sub>2</sub>} has been utilized as a highly effective catalyst in order to promote the following organic transformations under green, solvent-free and mild conditions: (i) the synthesis of 4<em>H</em>-pyrano[2, 3-<em>c</em>]pyrazoles from aromatic aldehydes, 3-methyl-1-phenyl-2-pyrazolin-5-one and malononitrile, (ii) the preparation of <em>α</em>-carbamatoalkyl-<em>β</em>-naphthols from arylaldehydes, <em>β</em>-naphthol and alkyl carbamates, and (iii) the production of <em>α</em>-amidoalkyl-<em>β</em>-naphthols from arylaldehydes, <em>β</em>-naphthol and amides.
N,N',N'-Tetramethylethylene-diaminium-N,N'-disulfonic acid chloride {[TMEDSA][Cl]2} Sulfonic acid-functionalized ionic liquid 4H-Pyrano[2,3-c]pyrazole α-Carbamatoalkyl-β-naphthol α-Amidoalkyl-β-naphthol
https://www.ajgreenchem.com/article_87655.html
https://www.ajgreenchem.com/article_87655_ced3fc931aedcd763a43e04438db07ce.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
One-pot synthesis of 1-amidoalkyl-2-naphthols catalyzed by nano-graphene oxide under solvent-free conditions
183
191
EN
Fatemeh
Hakimi
0000-0002-4580-4139
Department of Chemistry, Payame Noor University (PNU), 19395-3697, Tehran, Iran
fatemeh.hakimi@yahoo.com
Fatemeh
Mirjalili
Department of Chemistry, Payame Noor University (PNU), 19395-3697, Tehran, Iran
fatemeh.mirjalili@yahoo.com
Mehdi
Fallah-Mehrjardi
Department of Chemistry, Payame Noor University (PNU), 19395-3697, Tehran, Iran
fallah.mehrjerdi@pnu.ac.ir
10.22034/AJGC/2020.2.6
An efficient and eco-friendly procedure for the synthesis of 1-amidoalkyl-2-naphthols by the one-pot three-component reaction of various aldehydes, 2-naphthol and acetamide catalyzed by nano-graphene oxide under solvent-free conditions has been described. The presented method has several advantages such as high yields, easy purification, mild reaction conditions, easy work-up, survival of different functional groups, and short reaction times. Moreover, nano-graphene oxide is an easily synthesized, cheap, air and moisture stable, heterogeneous and green catalyst.The catalyst could simply be separated and recovered from the reaction mixture and reused in subsequent reactions without significant loss in activity.
1-Amidoalkyl-2-naphthols,Nano-graphene oxide,One-pot synthesis,Three-component reaction,Solvent-free conditions
https://www.ajgreenchem.com/article_88278.html
https://www.ajgreenchem.com/article_88278_9ffe89f5c5486497ff020eb7c3fcbda7.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Determination of methylparaben in some cosmetics and pharmaceutics using liquid-liquid extraction and spectrophotometric technique
192
201
EN
Mariam
Farag Ambarak
Department of Chemistry, Faculty of Science, University of Benghazi, Benghazi, Libya
mariam.ambarak@uob.edu.ly
10.22034/AJGC/2020.2.7
Parabens are compounds often added to cosmetics and pharmaceutics as preservatives for fungi and bacterial growth, but, recent studies have linked these compounds to several adverse side-effects such as cancer, miscarriage and infertility. The extraction of methyl paraben from (hand cream, body lotion, blusher, body cream, and bath foam) was studied using liquid-liquid extraction with ethyl acetate as a solvent, and double beam UV-spectrophotometer at wave length 282 nm. Calibrations are linear (correlation coefficient r>0.997) and the limit of detection was 2.358 μg/mL The concentrations of methyl paraben for the selected cosmetic samples were ranged from 0.077% to 0.451%.
parabens,pharmaceutics,Cosmetics,liquid-liquid extraction
https://www.ajgreenchem.com/article_89971.html
https://www.ajgreenchem.com/article_89971_78500167eda26c5c8b751b41a3509928.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Kinetics of thermal degradation of PMMA-based dental resins scraps
202
219
EN
Paulo
dos Santos Jr
UFPA, Faculty of Odontology, Belém-Brazil
p.bisi@yahoo.com.br
Haroldo Jorge
Ribeiro
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
mineiroeq@yahoo.com.br
Caio
Ferreira
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
caiocf7@hotmail.com
Lucas
Bernar
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
lucas.bernar7@gmail.com
Sammy
Jonatan Bremerc
Regenerative Energien, HTW-Berlin, Berlin-Germany
jonatan-bremer-berlin@web.de
Douglas Alberto Rocha
de Castro
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
douglascastro87@hotmail.com
Armando
Ferreira
UFPA, Faculty of Odontology, Belém-Brazil
armandocostaferreira@hotmail.com
Conceição de Maria Sales
da Silva
UFPA, Faculty of Odontology, Belém-Brazil
conceicao_odonto@yahoo.com.br
Maria Elizabeth Gemaque
Costa
UFPA, Faculty of Odontology, Belém-Brazil
gemaquebeth@yahoo.com.br
Marcelo
Santos
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
marceloenqui@bol.com.br
Sergio
Junior
UEA, Faculty of Chemical Engineering, Manaus-Brazil
duvoisin66@hotmail.com
Luiz
Pizarro Borges
IME-RJ, Section of Chemical Engineering, Rio de Janeiro-Brazil
luiz@ime.eb.br
Nélio Teixeira
Machado
UFPA, Institute of Technology, Faculty of Chemical Engineering, Belém-Brazil
machado@ufpa.br
10.22034/AJGC/2020.2.8
In this work, the cross-linked PPMA-based dental resins scraps were applied to pyrolysis to recover MMA (Methyl methacrylate). Thermal degradation of the cross-linked PPMA-based dental resins scraps was analyzed using TG/DTG to guide the operating condition. The pyrolysis was carried out in a reactor of 143 L, at 345 °C and 1.0 atmosphere. The reaction liquid products which were obtained at 30, 40, 50, 60, 70, 80, and 110 min, were physicochemically characterized for density, kinematic viscosity, and refractive index. The chemical composition of the reaction liquid products, obtained at 30, 40, 50, 60, 70, 80, and 110 min, was determined by GC-MS. The liquid phase yield was 55.50% (wt), while that of the gas phase was 31.69% (wt). The density, kinematic viscosity and refractive index of the reaction liquid products which were obtained at 30, 40, 50, 60, 70, 80, and 110 min, varied between 0.9227 and 0.9380 g/mL, 0.566 and 0.588 mm<sup>2</sup>/s, and 1.401 and 1.414, respectively. Moreover, it shows the percentage errors at the range of 0.74-2.36%, 7.40-10.86%, and 0.00-0.92%, respectively, as compared to the standard values for density, kinematic viscosity, and refractive index of pure MMA (Methyl metaclylate) at 20 °C. The GC-MS, identified in the reaction liquid products during pyrolysis, esters of carboxylic acids, alcohols, ketones, and aromatics, shows concentrations of MMA (Methyl metaclylate) between 88.003 and 98.975% (Area). The concentrations of MMA (Methyl metaclylate) in the liquid phase, between 30 and 80 min, reach purities above 98% (Area), decreasing drastically with increasing the reaction time after 100 min. Thus, it will be possible to depolymerize the cross-linked PPMA-based dental resins scraps by pyrolysis in order to recover MMA (Methyl methaclylate).
PMMA,Pyrolysis,Process Analysis,Kinetics,Recovery of MMA
https://www.ajgreenchem.com/article_91280.html
https://www.ajgreenchem.com/article_91280_f3c87d9e8aa5bf83e562a38452f6fb60.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Adsorption of 3-picrylamino-1,2,4-triazole on C60 surface as a green fuel: DFT studies
220
230
EN
Maryam
Godarzi
Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran
maryamgodarzi.8086@yahoo.com
Roya
Ahmadi
Department of Chemistry, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran
roya_ahmadi_chem@yahoo.com
Reza
Ghiasi
Department of Chemistry, Faculty of science, East Tehran Branch, Islamic Azad University, Tehran, Iran
rezaghiasi1353@hotmail.com
10.22034/AJGC/2020.2.9
In this study, the adsorption of 3-picrylamino-1,2,4-triazole (PATO) On the surface of fullerene (C<sub>60</sub>) was evaluated by density functional theory using, Becke, three-parameter and Lee-Yang-Parr (B3LYP). PATO as a green fuel, is such a green material and environmental friendly, because after combustion it produces excessive amounts of N<sub>2</sub> gas. Due to the importance of these materials in protecting environmental pollution as well as protecting fossil fuel reserves, it is necessary to research in this field. For this purpose, the structures of PATO, C<sub>60</sub>, and the PATO-C<sub>60</sub> complexes were optimized geometrically. Then, IR and Frontier molecular orbital calculations were performed on them. The calculated energies: Gibbs free energy changes (ΔG<sub>ad</sub>) and adsorption enthalpy changes (ΔH<sub>ad</sub>) revealed that the adsorption process of PATO-C<sub>60 </sub>complexes are experimentally feasible, spontaneous and exothermic. The specific heat capacity values (C<sub>V</sub>) showed the heat sensitivity has reduced significantly in the PATO-C<sub>60</sub> complexes. The N‒O and C‒N bond lengths and the density values demonstrated that PATO-C<sub>60</sub> complexes have higher explosive velocity and blasting pressure in comparison to the pure blasting materials without C<sub>60</sub>. The Frontier molecular orbital parameters such as band gap, chemical hardness, electrophilicity, chemical potential and charge capacity were also studied.
explosives,PATO,Fullerene (C60),Adsorption,Density functional theory
https://www.ajgreenchem.com/article_92110.html
https://www.ajgreenchem.com/article_92110_0a7743d164f8b6234a19c408604b2412.pdf
Sami Publishing Company
Asian Journal of Green Chemistry
2588-5839
2588-4328
4
2
2020
04
01
Green and selective oxidation of alcohols using MnO2 nanoparticles under solvent-free condition using microwave irradiation
231
238
EN
Salam
Ghafour Taher
Department of Chemistry, Faculty of Science and Health, Koya University Koya KOY45, Kurdistan Region – F.R. Iraq
salam.taher@koyauniversity.org
Karzan
Abdulkareem Omar
0000-0002-6694-6144
Department of Chemistry, Faculty of Science and Health, Koya University Koya KOY45, Kurdistan Region – F.R. Iraq
karzan.abdulkareem@koyauniversity.org
Bestoon
Mohammed Faqi-Ahmed
0000-0002-7600-1603
Department of Chemistry, Faculty of Science and Health, Koya University Koya KOY45, Kurdistan Region – F.R. Iraq
bestoon.mohammed@koyauniversity.org
10.22034/AJGC/2020.2.10
Alcohols are selectively oxidized to aldehydes using active manganese dioxide (MnO<sub>2</sub>) nanoparticles under solvent-free condition using microwave irradiation. The complete conversion of the alcohols to their corresponding aldehydes was achieved successfully within only 15 seconds of irradiation in microwave oven. The products of oxidation were characterized by TLC, IR, and Tollens' test, which showed the characteristic results of the desired aldehydes. This method is found to be fast, green, and a very easy procedure that could be applied for the oxidation of alcohols to aldehydes without further oxidation to carboxylic acids.
Green Oxidation of alcohols,Alcohol oxidation using metal oxides,synthesis of manganese nanoparticles
https://www.ajgreenchem.com/article_92192.html
https://www.ajgreenchem.com/article_92192_ae5f9921f9e95f6c10b19d93cdad8da3.pdf