ORIGINAL_ARTICLE
Emblica officinalis leaf extract mediated synthesis of zinc oxide nanoparticles for antibacterial and photocatalytic activities
ZnO nanoparticles have been synthesized via a simple green method using plant extract without the use of any other chemicals. The synthesized ZnO nanoparticles were characterized by UV–vis diffuse reflectance spectroscopy (UV-vis DRS), photoluminescence measurements (PL), X-ray diffraction (XRD), fourier transform infrared spectroscopy (FT-IR), field emission-scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), respectively. Photocatalytic activities of ZnO nanoparticles were evaluated by degradation of methylene blue under UV radiation. Moreover, the antibacterial activity of synthesized ZnO nanoparticles against S. aureus, S. paratyphi, V. cholerae, and E. coli are also screened.
https://www.ajgreenchem.com/article_81587_8e347949e4068972f5cb39149874dbd2.pdf
2019-10-01
418
431
10.33945/SAMI/AJGC.2019.4.1
Zinc oxide
Biosynthesis
Photocatalysis
Antibacterial Activity
Anbuvannan
Mari
anbuphy85@gmail.com
1
Department of Physics, Sri Akilandeswari Women’s College, Wandiwash-604408, Tamil Nadu, India
LEAD_AUTHOR
Ramesh
Mookkaiah
rameshm82phy@gmail.com
2
Department of Physics, M.V. Muthiah Government Arts College for Women, Dindigul- 624 001.Tamil Nadu, India
AUTHOR
Manikandan
Elayaperumal
manicsir@gmail.com
3
Department of Physics ,Thiruvalluvar University College of Arts & Science , Thennangur-604408. Tamil Nadu, India
AUTHOR
[1]. Das S.N., Kar J.P., Choi J.H., Lee T.I., Moon K.J., Myoung J.M. J. Phys. Chem. C, 2010, 114:1689
1
[2]. Huang M.H., Mao S., Feick H., Yan H., Wu Y., Kind H., Weber E., Russo R., Yang P. Science., 2001, 292:1897
2
[3]. Wang Z.S., Huang C.H., Huang Y.Y., Hou Y.J., Xie P.H., Zhang B.W., Cheng H.M. Chem. Mater., 2001, 13:678
3
[4]. Liu Z., Liu C., Ya J., Lei E. Renew. Energy., 2011, 36:1177
4
[5]. Lee C.J., Lee T.J., Lyu S.C., Zhang Y., Ruh H., Lee H.J. Appl. Phys. Lett., 2002, 81:3648
5
[6]. Sridevi D., Rajendran K.V. Bull. Mater. Sci., 2009, 32:165
6
[7]. Honma I., Hirakowa S., Yamada K., Bae J.M. Solid State Ionics.,1999, 118:29
7
[8]. Zeng J.H., Jin B.B., Wang Y.F. Chem. Phys. Lett., 2009, 472:90
8
[9]. Arumugam A., Karthikeyan C., Syedahamed Haja Hameed A., Gopinath K., Gowri S., Karthika V. Mater. Sci. Eng., 2015, 49:408
9
[10]. Sangeetha G., Rajeshwari S., Venckatesh R. Mater. Res. Bull., 2011, 46:2560
10
[11]. Azizi S., Ahmad M.B., Namvar F., Mohamad R. Mater. Lett., 2014, 116:275
11
[12]. Sangeetha N., Kumaraguru A.K. J. Nanobiotechnol., 2013, 11:39
12
[13]. Jayaseelan C.,Abdul Rahuman A., Vishnu Kirthi A., Marimuthu S., Santhoshkumara T., Bagavana A., Gaurav K., Karthik L., Bhaskara Rao K.V. Spectrochim. Acta A, 2012, 90:78
13
[14]. Rajiv P., Rajeshwari S., Venckatesh R. Spectrochim. Acta A, 2013, 112:384
14
[15]. Mahre M.B., Umaru B., Ojo N.A., Yahi D., Sa’idu A.S., Musa A.S., Bukola O.O. J.of Research in Forestry, Wildlife & Enviro., 2017,9:2141
15
[16]. Vidya C., Hirematha S., Chandraprabha M.N., Lourdu Antonyraja M.A., Venu Gopal I., Jaina A., Bansala K. Int. J. Curr. Eng. Technol., 2013, 2277:118
16
[17]. Ain Samat N., Md Nor R. Ceram. Int., 2013, 39:S545
17
[18]. Gnanasangeetha D., Saralathambavani D. Asian Acad. Res. J. Multidiscip., 2013, 1:164
18
[19]. Vivekanandhan S., Schreiber M., Mason C., Mohanty A.K., Misra M. Colloids Surf. B: Biointerfaces., 2014, 113:169
19
[20]. Elumalai K., Velmurugan S., Ravi S., Kathiravan V., Ashokkumar S. Spectrochim. Acta A, 2015, 136:1052
20
[21]. Ramesh M., Anbuvannan M., Viruthagiri G. Spectrochim. Acta A, 2015, 136:864
21
[22]. Anbuvannan M., Ramesh M., Viruthagiri G., Shanmugam N., Kannadasan N. Mat. Science Semiconduct. Process., 2015, 39:621
22
[23]. Anbuvannan M., Ramesh M., Viruthagiri G., Shanmugam N., Kannadasan N., Spec. Acta Part A: Molecul. Biomolecul. Spectr., 2015, 14:304
23
[24]. Anbuvannan M., Ramesh M., Manikandan E., Srinivasan R. Asian J. of Nanosci and Mat., 2018, 2:99
24
[25]. Senthilraja A., Subash B., Krishnakumar B., Rajamanickam D., Swaminathan M., Shanthi M. Mat. Sci. Semiconductor Proc., 2014, 22:83
25
[26]. Kelman D., Kashman Y., Rosenberg E., Ilan M., Iirach I., Loya Y. Aquat. Microb. Ecol., 2001, 24:9
26
[27]. Sangeetha G., Rajeshwari S., Venckatesh R. Mater. Res. Bull., 2011, 46:2560
27
[28]. Vanheusden K.V., Warren W.L., Seager C.H. J. Appl. Phys., 1996, 79:7983
28
[29]. Heo Y.W., Norton D.P., Pearton S.J. J. Appl. Phys., 2005, 98:073502
29
[30]. Lin B., Fu Z., Jia Y. Appl. Phys. Lett., 2001,79:943
30
[31]. Huang M.H., Wu Y., Feick H., Tran N., Weber E., Yang P. Adv. Mater., 2001, 13:113
31
[32]. Anbuvannan M., Inter. J. of Recent Scientific Research., 2017, 8:18501
32
[33]. Senthilkumar S.R., Sivakumar T. Int. J. Pharm. Pharmaceutical Sci., 2014, 6:461
33
[34]. Deng Y., Wang G., Li N., Guo L. J. Luminescence., 2009, 129:55
34
[35]. Anbuvannan M., Inter.J. of Recent Scientific Research., 2017, 8:19224
35
[36]. Ngoc Tien H., Hoang Luan V., Thuy Hoa L., Tri Khoa N., Hong Hahn S., Suk Chung J., Woo Shin E., Hyun Hur S. Chem. Eng. J., 2013, 229:126
36
[37]. Nipane S.V., Korake P.V., Gokavi G.S. Ceramics Int., 2015, 41:4549
37
[38]. Pirhashemi M., Habibi-Yangjeh A. App. Surface Sci., 2013, 283:1080
38
[39]. Zaman M.S., Haberer E.D. J. App. Phy., 2014, 116:154308
39
[40]. Anbuvannan M., Ramesh M., Viruthagiri G., Shanmugam N., Kannadasan N. Spectro. Acta Part A: Molecul. Biomolecul. Spec., 2015, 143:304
40
[41]. Gunalana S., Sivaraja R., Rajendran V. Prog. Nat. Sci. Mater. Int., 2012, 22:693
41
[42]. Manjunath K., Ravishankar T.N., Kumar D., Priyanka K.P., Varghese T., Raja Naika H., Nagabhushana H., Sharma S.C., Dupont J., Ramakrishnappa T., Nagaraju G. Mater. Res. Bul., 2014, 57:325
42
[43]. Shinde V.V., Dalavi D.S., Mali S.S., Hong C.K., Kim J.H., Pramod Patil P.S. App. Surface Sci., 2014, 307:495
43
[44]. Jan T., Iqbal J., Ismail M., Mansoor Q., Mahmood A., Ahmad A. App. Surface Sci., 2014, 308:75
44
ORIGINAL_ARTICLE
Hydrothermal and sol-gel low-temperature synthesis of tin, silver co-doped TiO2 nanoparticles with enhanced photocatalytic efficiency: artificial neural network modelling
Pure anatase TiO2 nanoparticles with various Ag and Sn contents were synthesized by hydrothermal and sol-gel low-temperature methods. Structural and morphological characterizations of synthesized nanoparticles were performed by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and N2 adsorption/desorption isotherm and brunauer-emmett-teller (BET) techniques. The effect of synthesis procedure on the crystalline structure, crystal size, surface area, pore size distribution and photocatalytic activity of synthesized samples were studied. The photocatalytic activity was tested vs. degradation of methylene blue (MB) under black light radiation. Ag/Sn-TiO2 nanoparticles synthesized by hydrothermal method showed higher photoactivity during the degradation of MB under black light irradiation because of being enhanced in the specific surface area, total pore volume, and its reduction in the crystallite size. An artificial neural network (ANN) comprising four input variables (mol% of dopant ions, photocatalyst dosage, initial dye concentration, and pH of the solution), eight neurons and an output variable (degradation efficiency %) was optimized, tested and validated for MB degradation by Ag/Sn-TiO2 nanoparticles synthesized via hydrothermal method. The results showed that the predicted data from the designed ANN model are in good agreement with the experimental data with a correlation coefficient (R2) of 0.979. A 98.9% photodegradation efficiency of MB was achieved by utilizing 0.07 mol% Ag and 0.03 mol% Sn co-doped TiO2 at pH = 12.
https://www.ajgreenchem.com/article_81659_0a4c782fd4129ea8a227f0088cb2b6ed.pdf
2019-10-01
432
454
10.33945/SAMI/AJGC.2019.4.2
Ag/Sn-TiO2 nanoparticles
Sol-gel low-temperature method
Photocatalytic activity
Artificial Neural Network
Robab
Mohammadi
mohammadi_rb@yahoo.com
1
Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, Iran
LEAD_AUTHOR
Mohammad
Isazadeh
isazadeh.m@yahoo.com
2
Department of Water Engineering, Faculty of Agriculture, University of Tabriz, Iran
AUTHOR
[1]. Kim Y.K., Kim E.Y., Whang C.M., Kim Y.H., Lee W.I. J. Sol-Gel Sci. Tech., 2005, 33:87
1
[2]. Sheikhnejad-Bishe O., Zhao F., Rajabtabar-DarvishiA., Khodadad E., Mostofizadeh A, Huang Y. Int. J. Electrochem. Sci., 2014, 9:4230
2
[3]. Li Y., Jiang Y., Peng S., Jiang F. J. Hazard. Mater., 2010, 182:90
3
[4]. Sun Z., Kim J.H., Zhao Y., Bijarbooneh F., Malgras V., Lee Y., Kang Y.M., Dou S.X. J. Am. Chem. Soc., 2011, 133:19314
4
[5]. Dehghani M., Nasseri S., Ahmadi M., Samaei M.R., Anushiravani A. J. Environ. Health Sci. Eng., 2014, 12:56
5
[6]. Nguyen T.B., Hwang M.J., Ryu K.S. Bull. Korean Chem. Soc., 2012, 33:243
6
[7]. Parra R., Ramajo L.A., Go´es M.S., Varela J.A., Castro M.S. Mater. Res. Bull., 2008, 43:3202
7
[8]. Yu C., Cai D., Yang K., Yu J.C., Zhou Y., Fan C. J. Phys. Chem.Solids., 2010, 71:1337
8
[9]. Jeong E.D., Borse P.H., Jang J.S., Lee J.S., Jung O.S., Chang H., Jin J.S., Won M.S.,Kim H.G. Ceramic Process. Res., 2008, 9:250
9
[10]. Li X., Lu J., Dai Y., Guo M., Huang B. 2012, Int. J. Photoenergy, 2012, 2012:7 pages
10
[11]. Khataee A.R., Kasiri M.B. J. Molecul. Catal. A: Chem., 2010, 331:86
11
[12]. Mohammadi R., Massoumi B. Russ. J. Phys. Chem. A., 2014, 88:1184
12
[13]. Barakat N.A.M., Kanjwal M.A., ChronakisI S., Kim H.Y. J. Mol. Catal. A: Chem., 2013, 366:333
13
[14]. Park J.Y., Lee I.H. J. Nanomater., 2014, 2014:6 pages
14
[15]. Mohammadi R., Massoumi B., Rabani M. Int. J. Photoenergy, 2012, 2012:7 pages
15
[16]. Mohammadi R. Desalin. Water. Treat., 2016, 57:22370
16
[17]. Ba-Abbad M.M., Kadhum A.A.H., Mohamad A.B., Takriff M.S., Sopian K. Int. J. Electrochem. Sci., 2012, 7:4871
17
[18]. Mohammadi R, Massoumi B., Eskandarloo H., Desalin. Water. Treat., 2015, 53:1995
18
[19]. Bagheri S., Ramimoghadam D., Termeh Yousefi A., Bee Abd Hamid S., Int. J. Electrochem. Sci., 2015, 10:3088
19
[20]. Yao S., Song S., Wang S. Desalin. Water. Treat., 2013, 51:7101
20
[21]. Rivera-Muñoz E.M., Huirache-Acuña R. Int. J. Mol. Sci., 2010, 11:3069
21
[22]. Georgekutty R., Seery M.K., Pillai S.C. J. Phys. Chem. C., 2008, 112:13563
22
[23]. Teoh W.Y., Scott J.A., Amal R. J. phys. Chem. Lett., 2012, 3:629
23
[24]. Seery M.K., George R., Floris P., Pillai S.C. J. Photochem. Photobiol. A: Chem., 2007, 18:258
24
[25]. Liu L., Li Y. Aerosol. Air Qual. Res., 2014, 14:453
25
[26]. Carp O., Huisman C.L., Reller A. Prog. Solid. State. Chem., 2004, 32:33
26
[27]. Zhao B., Chen F., Jiao Y., Yang H., Zhang J. J. Mol. Catal. A: Chem., 2012, 348:114
27
[28]. Sobana N., Muruganadham M., Swaminathan M. J. Mole. Catal. A., 2006, 258:124
28
[29]. Rawal S.B., Ojha D.P., Choi S.Y., Lee W.I. Bull. Korean Chem. Soc., 2014, 35:913
29
[30]. Rawal S.B., Chakraborty A.K., Lee W.I. Bull. Korean Chem. Soc., 2009, 30:2613
30
[31]. Murdoch M., Waterhouse G.I., Nadeem M.A., Metson J.B., Keane M.A., Howe R.F., Llorca J., Idriss H. Nature. Chem., 2011, 3:489
31
[32]. Frontistis Z., Daskalaki V.M., Hapeshi E., Drosou C., Fatta-Kassinos D., Xekoukoulotakis N.P., Mantzavinos D. J. Photochem. Photobiol. A: Chem., 2012, 240:33
32
[33]. Kasiri M.B., Aleboyeh H., Aleboyeh A. Environment. Sci. Technol., 2008, 42:7970
33
[34]. Primo A., Corma A., Carsia H. Phys. Chem. Chem. Phys., 2011, 13:886
34
[35]. Sanchooli M., Ghaffari Moghaddam M. J. Chem. Eng. Japan., 2012, 45:373
35
[36]. Emilio C.A., Magallanes J.F., Litter M.I. Anal. Chim. Acta., 2007, 595:89
36
[37]. Abdollahi Y., Zakaria A., Abbasiyannejad M., Fard Masoumi H.R., Ghaffari Moghaddam M., Amin Matori K., Jahangirian H., Keshavarzi A. Chem. Cent. J., 2013, 7:96
37
[38]. Abdollahi Y., Abdullah A.H., Zainal Z., Yusof N.A. Int. J. Chem., 2011, 3:31
38
[39]. Melián E.P., Díaz O.G., Rodríguez J.M.D., Colón G., Navío J.A., Macías M., Pena J.P. App. Catal. B: Environment., 2012, 127:112
39
[40]. Kim H.C., Lee S.H., Kim D.J., Choi J.W. Wat. Air. Soil. Pollut., 2013, 224:1459
40
[41]. Choi J.W, Lee S.Y., Lee S.H., Lee K.B., Kim D.J., Hong S.W. Wat. Air. Soil. Pollut., 2012, 223:2551
41
[42]. Sin J.C., Lam S.M., Mohamed A.R., Lee K.T. Int. J. Photoenergy, 2012, 2012:23 pages
42
[43]. Daneshvar N., Salari D., Khataee A.R. J. Photochem. Photobiol. A., 2003, 157:111
43
[44]. Silva C.G., Juárez R., Marino T., Molinari R., García H. J. Amer. Chem. Soc., 2010, 133:595
44
[45]. Zhao J., Hidaka H., Takamura A., Pelizzetti E., Serpone N. Langmuir. 1993, 9:1646
45
[46]. Lodha S., Jain A., Sharma V.K., Punjabi Indonesian P.B. J. Chem., 2008, 42:42
46
[47]. Gomathi Devi L., Kavitha R. RSC. Adv., 2014, 4:28265
47
[48]. Wang H.W., Lin H.C., Kuo C.H., Cheng Y.L., Yeh Y.C. J. Phys. Chem. Sol., 2008, 69:633
48
[49]. Wang W., Zhang J., Chen F., He D., Anpo M. J. Coll. Interface Sci., 2008, 323:182
49
[50]. Liu J., Zhao Y., Shi L., Yuan S., Fang J., Wang Z., Zhang M. Appl. Mater. Interfaces., 2011, 3:1261
50
[51]. Arpac E., Sayılkan F., Asilturk M., Tatar P., Kiraz N., Sayılkan H. J. Hazard. Mater., 2007, 140:69
51
[52]. Subash B., Krishnakumar B., Sreedhar B., Swaminathan M., Shanthi Superlattic M. Micro., 2013, 54:155
52
[53]. Liu J., Xu Z.B. Adv. Mater. Res., 2012, 472:157
53
[54]. Garson G.D. AI. Expert., 1991, 6:47
54
[55]. Aleboyeh A., Kasiri M.B., Olya M.E., Aleboyeh H. Dyes Pigm., 2008, 77:288
55
ORIGINAL_ARTICLE
Green synthesis and antibacterial activity of cadmium sulfide nanoparticles (CdSNPs) using Panicum sarmentosum
The plant sources can act as potential precursors for the synthesis of nanoparticles in non-hazardous ways as plants contain various secondary metabolites, acting as reducing and stabilizing agents for the reduction reaction to synthesize novel metallic nanoparticles. The green synthesized nanoparticles have been proven to control various diseases with less adverse effect. Thus, in this study, the green method for the preparation of cadmium sulfide nanoparticles using Panicum sarmentosum has been adopted. The synthesized CdSNPs were evaluated for their optical, structural, surface morphological and antibacterial properties. The CdSNPs were characterized by different techniques including UV–vis spectrophotometry, fourier transmission infrared spectroscopy (FT-IR), X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), X-ray fluorescence (XRF) and thermal gravimetric analysis (TGA). The antibacterial activity against Staphylococcus aureus and Escherichia coli was also carried out. The XRD pattern revealed the crystalline structure of CdSNPs. The SEM analysis showed the size and shape of the nanoparticles. XRF analysis confirmed the presence of cadmium and sulphur in nanoparticles. The presence of (OH), (NH) and carboxylic functional groups were confirmed by FTIR analysis. TGA results prove that CdSNPs are more thermally stable than plant material. The ecological friendly methods can generate simple, easy and cost-effective nanoparticles than chemical and physical approaches and have a potential to be used as antibacterial agents.
https://www.ajgreenchem.com/article_81759_00d1a07d4d13e9561672ebe130478485.pdf
2019-10-01
455
469
10.33945/SAMI/AJGC.2019.4.3
Scanning electron microscopy
X-ray Fluorescence
Thermal Gravimetric Analysis
Irshad Ul
Haq Bhat
irshadbhat78@gmail.com
1
Faculty of Earth Science, Universiti Malaysia Kelantan, Campus Jeli, 17600, Kelantan, Malaysia
LEAD_AUTHOR
Yong Sin
Yi
charlessyong@gmail.com
2
Faculty of Earth Science, Universiti Malaysia Kelantan, Campus Jeli, 17600, Kelantan, Malaysia
AUTHOR
[1]. Murray C.B., Kagan C.R., Bawendi M.G. Annu. Rev. Mater. Sci., 2000, 30:545
1
[2]. Hu J., Odom T.W., Lieber C.M. Acc. Chem. Res., 1999, 32:435
2
[3]. Kar S., Chaudhuri S. Synth. React. Inorg. Metal-Organic Nano-Metal Chem., 2006, 36:289
3
[4]. Yang G., Qin D., Du X., Zhang L., Zhao G., Zhang Q., Wu J. J. Alloy. Compd., 2014, 604:181
4
[5]. Tayade R.J. Natarajan T.S., Bajaj H.C. Industrial & Engineering Chemistry Research, 2009, 48:10262
5
[6]. Yang H., Huang C., Li X., Shi R., Zhang K. Mater. Chem. Phys., 2005, 90:155
6
[7]. Pardo-Yissar V., Katz E., Wasserman J., Willner I. J. Am. Chem. Soc., 2003, 125:622
7
[8]. Zhao J., Bardecker J.A., Munro A.M., Liu M.S., Niu Y., Ding I.K., Luo J., Chen B., Jen A.K.Y., Ginger D.S. Nano Lett., 2006, 6:463
8
[9]. Raziya S., Durga B., Rajamahanthe S.G., Govindh B., Annapurna N. Int. J. Adv. Technol. Eng. Sci., 2016, 4:220
9
[10]. Xaba T., Moloto M.J., Moloto N. Mater. Lett., 2015, 146:91
10
[11]. Naseem T., Farrukh M.A. Journal of Chemistry, 2015, 2015:7 page
11
[12]. Prasad K.S., Amin T., Katuva S., Kumari M., Selvaraj K. Arabian J. Chem., 2017, 10:S3929
12
[13]. Goud B.S., Suresh Y., Annapurna S., Singh A.K., Bhikshamaiah G. Mater. Today: Proce., 2016, 3:4003
13
[14]. Rao M.D., Pennathur G. Mater. Res. Bull., 2017, 85:64
14
[15]. Hatti-Kaul R., Törnvall U., Gustafsson L., Börjesson P. Trends biotech., 2007, 25:119
15
[16]. Bai H.J., Zhang Z.M., Guo Y., Yang G.E. Colloid. surfaces B: Biointerfaces, 2009, 70:142
16
[17]. Isarov A.V., Chrysochoos J. Langmuir, 1997, 13:3142
17
[18]. Wilson J.R., Brown R.H. Crop Sci., 1983, 23:1148
18
[19]. Allison S.D., Chang B., Randolph T.W., Carpenter J.F. Arch. Biochem. Biophys., 1999, 365:289
19
[20]. O'Brien P., Saeed T. J. Crystal growth, 1996, 158:497
20
[21]. Barnes W.L., Dereux A., Ebbesen T.W. Nature, 2003, 424:824
21
[22]. Baset S., Akbari H., Zeynali H., Shafie M. Digest Journal of Nanomaterials and Biostructures, 2011, 6:709
22
[23]. Silverstein R.M., Bassler G.C., Morrill T.C., Spectrometric Identification of Organic Compounds. 4th ed. New York: John Wiley and Sons, 1981; p x + 419
23
ORIGINAL_ARTICLE
Imidazole mediated synthesis of spirooxindoles in water using isatin as a privileged scaffold
This work describes the synthesis of complex small molecules spirooxindoles using imidazole as an efficient organocatalyst. The three components coupling reactions of isatin, malononitrile and enolizable 4-hydroxycoumarin were performed in water as a green solvent. The reaction is done with imidazole an amphoteric organocatalyst to construct spiro-molecules in high yields. The significant features of this protocol are neutral reaction condition, readily available low cost catalyst, metal free, strong acid/base free, and reusable reaction medium with no column chromatography separation. This methodology is useful for the easy access of structurally complex, highly functionalized spirooxindole molecules with important medicinal chemistry applications.
https://www.ajgreenchem.com/article_81802_cb6a9db859fb81c2ab80881fb37f5882.pdf
2019-10-01
470
482
10.33945/SAMI/AJGC.2019.4.4
Imidazole
Spirooxindole
Water
Multicomponent reaction
Organocatalysis
Md. Nasim
Khan
nasimiitp@gmail.com
1
Iqra Pharmaceuticals, Nutanhat, Burdwan, West Bengal-713147, India
LEAD_AUTHOR
Digvijaysinh K.
Parmar
parmardk@outlook.com
2
Diu College, DHES, Diu (U.T)- 362520, India
AUTHOR
Hardik B.
Bhatt
bhatthardik_msc@yahoo.com
3
Om College of Science, Junagadh-Gujrat-362310, India
AUTHOR
[1]. Zhu J., Bienayme H. Multicomponent Reactions; Wiley-VCH: Weinheim Germany, 2005
1
[2]. Zhu J., Wang Q., Wang M. Multicomponent Reactions in Organic Synthesis; Wiley-VCH: Weinheim Germany, 2014
2
[3]. Jung G. Combinatorial Chemistry: Synthesis, Analysis, Screening; Wiley-VCH: Weinheim Germany, 2008; p 125
3
[4]. Trabocchi A. Diversity-Oriented Synthesis: Basics and Applications in Organic Synthesis, Drug Discovery, and Chemical Biology; Wiley: Hoboken New Jersey, 2013; p 29
4
[5]. Zarganes-Tzitzikas T., Dömling A. Org. Chem. Front., 2014, 1:834
5
[6]. Weber L. Cur. Med. Chem., 2002, 9:2085
6
[7]. Sunderhaus J.D., Martin S.F. Chemistry, 2009, 15:1300
7
[8]. Kaur M., Singh M., Chadha N., Silakari O. Eur. J. Med. Chem., 2016, 123:858
8
[9]. Ye N., Chen H., Wold E.A., Shi P.Y., Zhou J. ACS Infect. Dis., 2016, 2:382
9
[10]. Yu B., Yu D.Q., Liu H.M. Eur. J. Med. Chem., 2015, 97:673
10
[11]. Sun Y., Liu J., Jiang X., Sun T., Liu L., Zhang X., Ding S., Li J., Zhuang Y., Wang Y., Wang R. Sci. Rep., 2015, 5:13699
11
[12]. Baran P.S., Richter J.M. J. Am. Chem. Soc., 2005, 127:15394
12
[13]. Edmondson S., Danishefsky S.J., Sepp-Lorenzino L., Rosen N. J. Am. Chem. Soc., 1999, 121:2147
13
[14]. Saraswat P., Jeyabalan G., Hassan M.Z., Rahman M.U., Nyola N.K. Synth. Commun., 2016, 46:1643
14
[15]. Panda S.S., Jones R.A., Bachawala P., Mohapatra P.P. Mini Rev. Med. Chem., 2017, 17:1515
15
[16]. Zheng Y.J., Tice C.M. Expert Opin. Drug Discov. 2016, 11:831
16
[17]. Wang S., Sun W., Zhao Y., McEachern D., Meaux I., Barriere C., Stuckey J.A., Meagher J.L., Bai L., Liu L., Hoffman-Luca C.G., Lu J., Shangary S., Yu S., Bernard D., Aguilar A., Dos-Santos O., Besret L., Guerif S., Pannier P., Gorge-Bernat D., Debussche L. Cancer Res., 2014, 74:5855
17
[18]. Singh G.S., Desta Z.Y. Chem. Rev., 2012, 112:6104
18
[19]. Pal S., Khan M.N., Karamthulla S., Choudhury L.H. Tetrahedron Lett., 2015, 56:359
19
[20]. Pal S., Khan M.N., Karamthulla S., Abbas S.J., Choudhury L.H. Tetrahedron Lett., 2013, 54:5434
20
[21]. Karamthulla S., Pal S., Khan M.N., Choudhury L.H. RSC Adv., 2013, 13:15576
21
[22]. Molla A., Ranjan S., Rao M.S., Dar A.H., Shyam M., Jayaprakash V., Hussain S. ChemistrySelect, 2018, 3:8669
22
[23]. Sadat-Ebrahimi S.E., Haghayegh-Zavareh S.M., Bahadorikhalili S., Yahya-Meymandi A., Mahdavi M., Saeedi M. Synth. Commun., 2017, 47:2324
23
[24]. Safaei-Ghomi J., Nazemzadeh S. H., Shahbazi-Alavi H. Catal. Commun., 2016, 86:14
24
[25]. Singh N.G., Lily M., Devi S.P., Rahman N., Ahmed A., Chandra A.K., Nongkhlaw R. Green Chem., 2016, 18:4216
25
[26]. Brahmachari G., Banerjee B. Asian J. Org. Chem., 2016, 5:271
26
[27]. Baghernejad M., Khodabakhshi S., Tajik S. New J. Chem., 2016, 40:2704
27
[28]. Molla A., Hussain S. RSC Adv., 2016, 6:5491
28
[29]. Nasseri M.A., Kamali F., Zakerinasab B. RSC Adv., 2015, 5:26517
29
[30]. He T., Zeng Q.Q., Yang D.C., He Y.H., Guan Z. RSC Adv., 2015, 5:37843
30
[31]. Khazaei A., Zolfigol M. A., Karimitabar F., Nikokar I., Moosavi-Zarec A. R. RSC Adv., 2015, 5:71402
31
[32]. Satasia S.P., Kalaria P.N., Avalani J.R., Raval D.K. Tetrahedron, 2014, 70:5763
32
[33]. Thakur A., Tripathi M., Rajesh U.C., Rawat D.S. RSC Adv., 2013, 3:18142
33
[34]. Saluja P., Aggarwal K., Khurana J.M. Synth. Commun., 2013, 43:3239
34
[35]. Hasaninejad A., Golzar N., Beyrati M., Zare A., Doroodmand M.M. J. Mol. Catal. A Chem., 2013, 372:137
35
[36]. Nasseri M.A., Sadeghzadeh S.M. J. Iran Chem. Soc., 2013, 10:1047
36
[37]. Guo R.Y., An Z.M., Mo L.P., Wang R.Z., Liu H.X., Wang S.X., Zhang Z.H. ACS Comb. Sci.,2013,15:557
37
[38]. Mohammadi Ziarani G., Hosseini Mohtasham N., Lashgari N., Badiei A., Amanlou M., Bazlc R. J. Nanostruct., 2013, 2:489
38
[39]. Safaei H.R., Shekouhy M., Rahmanpur S., Shirinfeshan A. Green Chem., 2012,14:1696
39
[40]. Hamadi H., Gholami M., Khoobi M. International J. Heterocyclic Chem., 2011, 1:1
40
[41]. Karimi A.R., Sedaghatpour F. Synthesis, 2010,10:1731
41
[42]. Baer D.R., Munusamy P., Thrall B.D. Biointerphases, 2016, 11:04B401
42
[43]. Karakoti A.S., Munusamy P., Hostetler K., Kodali V., Kuchibhatla S., Orr G., Pounds J.G., Teeguarden J.G., Thrall B.D., Baer D.R. Surf. Interface Anal., 2012, 44:882
43
[44]. Baer D.R. Front. Chem., 2018, 6:145
44
[45]. Bertelsen S., Jorgensen K.A. Chem. Soc. Rev., 2009, 38:2178
45
[46]. Dalpozzo R., Bartoli G., Bencivenni G., Chem. Soc. Rev., 2012, 41:7247
46
[47]. Qin Y., Zhu L., Luo S. Chem. Rev., 2017, 117:9433
47
[48]. Verma S.K., Acharya B.N., Kaushik M.P. Org. Lett., 2010, 12:4232
48
[49]. Huang X.G., Liu J., Ren J., Wang T., Chen W., Zeng B.B. Tetrahedron., 2011, 67:6202
49
[50]. Guan X.Y., Shi M. Org. Biomol. Chem., 2008, 6:3616
50
[51]. Khan M.N., Pal S., Karamthulla S., Choudhury L.H. RSC Adv., 2013, 4:3732
51
[52]. Huang C.N., Kuo P.Y., Lin C.H., Yang D.Y. Tetrahedron, 2007, 63:10025
52
ORIGINAL_ARTICLE
Solvent-free synthesis for imidazole-1-yl-acetic acid hydrochloride: an intermediate for zoledronic acid
A convenient and environmentally-friendly protocol for the preparation of imidazol-1-yl-acetic acid hydrochloride is described via solvent-free N-alkylation of imidazole by tert-butyl chloroacetate, the obtained imidazol-1-yl-acetic acid tert-butyl ester was hydrolyzed in water and treated with hydrochloric acid to get imidazol-1-yl-acetic acid hydrochloride in good yields. Unlike the previously reported methods, this two step process is completely free from the use of hazardous solvents, besides, it has high yielding and been characterized by simple and easy work-up procedure. Imidazol-1-yl-acetic acid hydrochloride produced by the described method is converted into zoledronic acid monohydrate of medicinal use.
https://www.ajgreenchem.com/article_81841_2ed332c64657d29578768215505495bf.pdf
2019-10-01
483
491
10.33945/SAMI/AJGC.2019.4.5
Imidazol-1-yl-acetic acid hydrochloride
N-alkylation
Solvent-free
Hydrolysis
zoledronic acid
Chandra Kant
Belwal
belwalck@gmail.com
1
Research and Process Development, Sterling Biotech Ltd., Masar, Jambusar State Highway, Vadodara, Gujarat, India, Pin code-391421
LEAD_AUTHOR
Jaimin
Patel
jim28982@yahoo.com
2
Research and Process Development, Sterling Biotech Ltd., Masar, Jambusar State Highway, Vadodara, Gujarat, India, Pin code-391421
AUTHOR
[1]. Sorbera L.A., Rabasseda X., Castaner J. Drugs Fut., 2000, 25:259
1
[2]. Brown D.L., Robbins R. J. Clin. Pharmacol., 1999, 39:651
2
[3]. Cheer S.M., Noble S. Drugs, 2001, 61:799
3
[4]. Ratrout S.S., Al Sarabi A.M., Sweidan K.A. Pharm. Chem. J., 2015, 48:835
4
[5]. Yadav R.P., Shaikh Z.G., Mukarram S.M.J., Kumar Y. European Patent, EP1963345A2, 2008
5
[6]. Muddasani P.R., Vattikuti U.R., Kagitha R.R., Nannapaneni V.C. Indian Patent, 202056, 2007
6
[7]. Muddasani P.R., Vattikuti U.R., Nannapaneni V.C. PCT Int. Pat. Appl., WO2005/063717, 2005
7
[8]. Singh S.K., Manne N., Ray P.C., Beilstein P.M. J. Org. Chem., 2008, 4:42
8
[9]. Aliabad J.M., Hosseini M., Yavari I., Rouhani M. The 20th International Electronic Conference on Synthetic Organic Chemistry.
9
[10]. Martin K., Benes M., Pis J. European Patent, EP 2192126 A1, 2010
10
ORIGINAL_ARTICLE
Bioactive principle loaded gold nanoparticles as potent anti-melanoma agent: green synthesis, characterization, and in vitro bioefficacy
The present communication warrants the presence of significant anti-melanoma bioefficacy in the native bark ethanolic extract (65.15%) of the plant Madhuca longifolia. A family of seven flavonoids has been ascertained in the bark ethanolic extract of the target plant using HPLC-ESI-QTOF-MS analysis as bioactive constituents. Statistically, significant (p <0.05)enhancement in the anti-melanoma bioefficacy (85.15%) has been successfully attempted, reaching near to the level of reference (Cyclophosphamide drug) using bioactive principle (flavonoid) loaded gold nanoparticles (F@AuNp). In vitro anti-melanoma bioefficacy has been measured against two melanoma cell lines (B16F10 and A375) using MTT and SRB bioassays. Noticeably, the native bark extract and F@AuNp did not show any toxicity towards normal lymphocyte cells, highlighting their safe and non-toxic nature. The pathway of observed anti-melanoma efficacy of (F@AuNp) has been discussed based on our experimental findings on percent inhibition in mice and human melanoma cell lines, production of intracellular reactive oxygen species, the release of nitric oxide, and increase caspase-3 activities. The native bark extract of the plant M. longifolia and its bioactive principle loaded gold nanoparticles possess bright prospects for the development of complimentary herbal nanomedicine for scaling-up the anti-melanoma bioefficacy.
https://www.ajgreenchem.com/article_82027_2f2d782d806bc842b721c2c1a4b723ad.pdf
2019-10-01
492
507
10.33945/SAMI/AJGC.2019.4.6
Madhuca longifolia
anti-melanoma bioefficacy
bioactive principle
enhancement in bioefficacy
F@AuNp
Saurabh
Yadav
saurabhy001@gmail.com
1
Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra-282005, India
AUTHOR
Mukti
Sharma
muktisharma90@gmail.com
2
Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra-282005, India
AUTHOR
Narayan
Ganesh
nganeshresrarch@gmail.com
3
Jawaharlal Nehru Cancer Hospital & Research Center, Bhopal-462001, India
AUTHOR
Shalini
Srivastava
dei.shalinisrivastava@gmail.com
4
Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra-282005, India
AUTHOR
Man Mohan
Srivastava
dei.smohanm@gmail.com
5
Department of Chemistry, Faculty of Science, Dayalbagh Educational Institute, Dayalbagh, Agra-282005, India
LEAD_AUTHOR
[1]. Siegel R.L., Miller K.M., Jemal A. Cancer J. Clin., 2017, 67:7
1
[2]. Fitzmaurice C., Akinyemiju T.F., Lami Al., Rawaf F.H., Rawaf D.L. JAMA Oncol., 2018, 4:1553
2
[3]. Panda S. Indian J. Dermatol., 2010, 55:373
3
[4]. Feller L., Khammissa R.A.G., Kramer B., Altini M., Lemmer J. Head Face Med., 2016, 12:11
4
[5]. Chen J., Shao R., Zhang X. D., Chen C. Int. J. Nanomedicine., 2013, 8:2677
5
[6]. Chidambaram M., Manavalan R., Kathiresan K. J. Pharm. Pharm. Sci., 2011, 14:67
6
[7]. Lin G., Mi P., Chu C., Zhang J., Liu G. Adv. Sci., 2016, 3:1
7
[8]. Khoobchandani M., Ganesh N., Gabbanini S., Valgimigli L., Srivastava M.M. Fitoterapia, 2011, 82:647
8
[9]. Kalpna D.R., Mital J.K., Sumitra V.C. Academic Press of Elsevier, UK, 2013
9
[10]. Ahirwar R.P., Tripathi J., Singh R. Int. J. Appl. Res., 2017, 3:818
10
[11]. Cencic A., Chingwaru W. Nutrients, 2010, 2:611
11
[12]. Cragg G.M., Newman D.J. J. Ethnopharmacol., 2005, 100:72
12
[13]. Nobili A., Garattini S., Mannucci P.M. JOC., 2011, 1:28
13
[14]. Kundu P., Das M., Kalpalata Tripathy K., Sahoo S.K. ACS Chem. Neurosci., 2016, 7:1658
14
[15]. Bi D., Zhao L., Yu R., Li H., Guo Y., Wang X., Han M. Drug Delivery, 2018, 25:564
15
[16]. Ahmed S., Ahmad M., Swami B.L., Ikram S. J. Adv. Res., 2016, 7:17
16
[17]. Wink M. Medicine., 2015,2:251
17
[18]. Kuppusamy P., Yusoff M.M., Maniam G.P., Govindan N. Saudi Pharm. J., 2016, 24:473
18
[19]. Sharma M., Yadav S., Srivastava M., Ganesh N., Srivastava S. Asian J. Nanosci. Mater., 2018, 1:244
19
[20]. He X., Hwang H.M. J. Food Drug Anal., 2016, 24:671
20
[21]. Bonifacio B.V., Silva P.B., Ramos M.A., Negri K.M., Bauab T.M., Chorilli M. Int. J. Nanomedicine., 2014, 9:1
21
[22]. Zhang M., Viennios E., Xu C., Merlin D. Tissue Barriers., 2016, 4:e1134415
22
[23]. Gaikwad R.D., Ahmed L., Khalid S., Swamy P. Pharma. Biol., 2009, 47:592
23
[24]. Akshatha K.N., Murthy S.M., Lakshmidevi N. IJLPR., 2013, 3:44
24
[25]. Jha D., Mazumder P.M. Asian Pacific J. Trop. Med., 2018, 11:9
25
[26]. Skenhan P., Storeng R., Scudiero D. J. Natl. Cancer Inst., 1990, 82:1107
26
[27]. Orellana E.A., Kasinski A.L. Bio Protoc., 2016, 6:21
27
[28]. Roy A., Ganguly A., BoseDasgupta S., Das B.B., Pal C., Jaisankar P., Majumder H.K. Mol. Pharm., 2008, 74:1292
28
[29]. Mahapatra S.K., Chakaraborty S.P., Das S., Roy S. Oxid. Med. Cell Longev., 2009, 2:222
29
[30]. Mollick M.M.R., Bhowmick B., Mondal D., Maity D., Rana D., Dash S.K., Chattopadhyay S., Roy S., Sarkar J., Acharya K., Chakarborty M., Chattopadhyay D. RSC Adv., 2014, 4:37838
30
[31]. Patil S.A., Patil D.A. Nat. Prod. Rad., 2007, 6:2
31
[32]. Akshatha K.N., Murthy S.M., Lakshmidevi N. IJLPR., 2013, 3:44
32
[33]. Wojdylo A., Oszmianski J., Czemerys R. Food Chem., 2007, 105:940
33
[34]. Zhang Y.J., Gan R.Y., Li S., Zhou Y., Li A.N., Xu D.P., Li H.B. Molecules, 2015, 20:1
34
[35]. Madhe S., Bansal P., Srivastava M.M. Appl Nanosci., 2014, 4:153
35
[36]. Kasote D.M., Katyare S.S., Hegde M.V., Bae H. Int. J. Biol. Sci., 2015, 11:982
36
[37]. Osonga F.J., Yazgan I., Kariuki V., Luther D., Jimenez A., Le P., Sadik O.A. RSC Adv., 2016, 6:2302
37
[38]. Kumar B., Smita K., Cumbal L., Camacho J., Hernández-Gallegos E., Chavez-Lopez M.D.G., Grijalva M., Andrade K. Mater. Sci. Eng. C., 2016, 62:725
38
[39]. Haselsberger K., Peterson D.C., Thomas D.G., Darling J.L. Anticancer Drugs., 1996, 7:331
39
[40]. Grigalius I., Petrikaite V. Molecules, 2017, 22:1
40
[41]. Ballesta M.C.M., Izquierdo A.G., Viguera C.G., Perles R.D. Foods, 2018, 7:2
41
[42]. Kim J., Kim J., Bae J.S. Exp. Mol. Med., 2016, 48:1
42
[43]. Habib S., Ali A. Indian J. Clin. Biochem., 2011, 26:3
43
ORIGINAL_ARTICLE
Synthesis and anti-microbial activities of azomethine and aminomethyl phenol derivatives
A series of azomethine and aminomethyl phenol derivatives has been synthesized and characterized by mass, IR, and NMR spectral techniques.In vitro antimicrobial activities of all these compounds were evaluated against different gram-positive and gram-negative bacterial and fungal strains by measuring zone of inhibition using agar diffusion method. Results of antimicrobial screening indicated that the compound 4a was the most active antimicrobial agent (100 µg/mL). The compounds 3a, 4e, 4f were exhibited best in vitro anti-microbial activity against the gram positive bacterial strains such as Bacillus subtilis, Micrococcus luteus and gram negativebacterialstrain Salmonella typhi andfungalstrain Candida albicans.
https://www.ajgreenchem.com/article_82297_42d37f04ee4e6d5e3dded3cea8f89bbc.pdf
2019-10-01
508
517
10.33945/SAMI/AJGC/2019.4.7
Aldehyde
Azomethines
Aminomethyl phenol
Antibacterial Activity
Antifungal activity
Sivakumar
Matam
msivakumar900@gmail.com
1
Department of Chemistry, The Gandhigram Rural Institute-Deemed to be University, Gandhigram, Dindigul district, Tamilnadu-624 302, India
AUTHOR
Prabakaran
Kaliyan
prabasathesh@gmail.com
2
Department of Chemistry, The Gandhigram Rural Institute-Deemed to be University, Gandhigram, Dindigul district, Tamilnadu-624 302, India
AUTHOR
Padmavathy
Sethuramasamy
padhusethu@gmail.com
3
Department of Zoology and Microbiology, Thiagarajar College, Madurai, Tamil Nadu, India
AUTHOR
Seenivasa Perumal
Muthu
mspchem99@gmail.com
4
Department of Chemistry, The Gandhigram Rural Institute-Deemed to be University, Gandhigram, Dindigul district, Tamilnadu-624 302, India
LEAD_AUTHOR
[1]. Lu J., Li C., Chai Y.F., Yang D.Y., Sun C.R. Bioorg. Med. Chem. Lett., 2012, 22:5744
1
[2]. Cheng L.X., Tang J.J., Luo H., Jin X.L., Dai F., Yang J., Qian Y.P., Li X.Z., Zhou B. Bioorg. Med. Chem. Lett., 2010, 20:2417
2
[3]. Franco D.C.Z., Carvalho G.S.G., Rocha P.R., Teixeira R.S., Silva A.D., Raposo N.R.B. Molecules, 2012, 17:11816
3
[4]. Niazi S., Javali C., Paramesh M., Sivaraja S. Int. J. Pharm. Pharm. Sci., 2010, 2:108
4
[5]. Suresh R., Kamalakkannan D., Ranganathan K., Arulkumaran R., Sundararajan R., Vijayakumar S., Sathiyamoorthi K., Mala V., Vanangamudi G., Thirumurthy K., Thirunarayanan G., Sakthinathan S.P., Mayavel P. Spectrochim. Acta, Part A.Molecul, Biomolecul, Spectros., 2013, 101:239
5
[6]. Misra S., Pandeya K.B., Tiwari A.K., Ali A.Z., Saradamani T., Agawane S.B., Madhusudana K. Med. Chem. Res., 2011, 20:1431
6
[7]. Iqbal A., Siddiqui H.L., Ashraf C.M., Bukhari M.H., Akram C.M. Chem. Pharm. Bull., 2007, 55:1070
7
[8]. Paula F.R., Jorge S.D., Almedia L.V., Pasqualoto K.F.M., Tavares L.C. Bioorg. Med. Chem., 2009, 17:2673
8
[9]. Shi L., Ge H.M., Tan S.H., Li H.Q., Song Y.C., Zhu H.L., Tan X.R. Eur. J. Med. Chem., 2007, 42:558
9
[10]. Kuzamin V.E., Artemenko A.G., Lozytska R.N., Fedtchouk A.S., Lozitsky V.P., Muratov E.N. Environ. Res., 2005, 16:219
10
[11]. Supuram C.T., Barboiu M., Luca C., Pop E., Brewster M.E., Dinculescu A. Eur. J. Med. Chem., 1996, 31:597
11
[12]. Rathelot P., Azas N., El-Kashef H., Delmas F., Di giorgio C., David P.T., Maldonado J., Vanelle P. Eur. J. Med. Chem., 2002, 37:671
12
[13] . Babaev E.R. Petroleum chem., 2006, 46:206
13
[14] . Petrovic Z.D., Dorovic J., Simijonovic D., Petrovic V.P., Markovic Z. RSC Adv., 2015, 5:24094
14
[15]. Rahman F.U., Li Z.T., Ali A., Lin Y., Guo R., Wang W.K., Wang H., Zhang D.W. Dalton Trans., 2015, 44:9872
15
[16]. Zhang M., Luo F., Gong Y. J. Org. Chem., 2014, 79:1335
16
[17]. Dubey R.K., Singh A.P., Dwivedi N. Phosphorus, Sulfur Silicon Relat. Elem., 2012, 187:1038
17
[18]. Niu C., Zhao L., Ouyang J., Fang T., Deng X., Ma H., Zhang J., Na N., Han J. Langmuir, 2014, 30:2351
18
[19]. Das S., Das V.K., Saikia L., Thakur A.J. Green Chem. Lett. Rev., 2012, 5:457
19
[20]. Cimarelli C., Palmieri G., Volpini E. Tetrahedron, 2001, 57:6089
20
[21] . Tabane T.H., Singh G.S. Proc. Natl. Acad. Sci. India, Sect. A Phys. Sci., 2014, 84:517
21
[22] . Tang Z., Zhu Z., Xia Z., Liu H., Chen J., Xiao W., Ou X. Molecules, 2012, 17:8174
22
[23]. Kamble R.D., Gacche R.N., Hese S.V., Dawane B.S., Meshram R.J., Kote J.R. Med. Chem. Res., 2015, 24:1077
23
[24] . Karaka A., Elmali A., Unver H., Svoboda I. J. Mol. Struct., 2004, 702:103
24
[25]. Arod F., Gardon M., Pattison P., Chapuis G. Acta Crysta. A., 2005, 61:0317
25
[26]. Holt J.G., Krieg N.R., Sneath P.H.A., Staley J.T., Williams S.T. Bergey’s Manual of Determinative Bacteriology, Williams and Wilkins Publisher, 9th Edition, Baltimore, 1994, p. 786
26
[27]. Faller P.M.A., Jones R.N., Messer S.A., Edmond M.B., Wenzel R.P. Diagn. Microbiol. Infect. Dis., 1998, 31:327
27
[28]. Lunel F.M.V., Meis J.F.G.M., Voss A. Diagn. Microbiol. Infect. Dis., 1999, 34:213
28
ORIGINAL_ARTICLE
Identification of lectins from the seeds of Bangladeshi plants Sesbania bispinosa and Senna occidentalis by hemagglutination assay
The hemagglutination assay is a simple and easy method to specify a lectin. An activelectinagglutinates erythrocytes by recognizing a carbohydrate on the cell surface and forming a cross-linked network in suspension. The assay is traditionally performed on a microtiter plate, where the lectin solution is serially diluted and the minimum concentration of a lectin causing agglutination is detected. The crude extract of Senna occidentalis and Sesbania bispinosa seedscontain considerable amount of protein. It was found that 10 gm of Sesbania bispinosaand Senna occidentalis seeds contain about 12.6 mg/mL and 9.8 mg/mL of protein and minimum agglutination concentration was found to be 0.393 mg/mL for Sesbania bispinosa in each group of human erythrocytes (A, B, O and AB) and 0.613 mg/mL for Senna occidentalis in chicken erythrocytes. Finally, the hemagglutination assay confirmed that possible lectins have been presented in the Sesbania bispinosa and Senna occidentalisplant sources.
https://www.ajgreenchem.com/article_82456_f9247d2633e88f8481f9b8660cfce481.pdf
2019-10-01
518
524
10.33945/SAMI/AJGC/2019.4.8
Hemagglutination
lectin
Blood group
Sesbania bispinosa
Senna occidentalis
Mst. Jesmin
Sultana
jssumi8@gmail.com
1
Department of Materials Science and Engineering, Faculty of Engineering, University of Rajshahi, Rajshahi, Bangladesh
LEAD_AUTHOR
Fazle Rabbi
Shakil Ahmed
frshakil@gmail.com
2
Department of Pharmacy, Khwaja Yunus Ali University, Sirajgonj, Bangladesh
AUTHOR
M. Taufiq
Alam
3
Department of Applied Chemistry and Chemical Engineering, Faculty of Engineering,University of Rajshahi, Rajshahi, Bangladesh
AUTHOR
[1]. Lis H., Sharon N. Chem. Rev., 1998, 98:637
1
[2]. Van Damme E.J.M., Peumans W.J., Barre A., Rougé P. Crit. Rev. Plant Sci., 1998, 17:575
2
[3]. Etzler M.E. Academic Press Inc Orlando., 1986, 371
3
[4]. Konkumnerd W., Karnchanatat A., Sangvanich P. J. Sci. Food Agric., 2010, 90:1920
4
[5]. Sitohy M., Doheim M., Badr H. Food Chem., 2007, 104:971
5
[6]. Tian Q., Wang W., Miao C., Peng H., Liu B., Leng F., Dai L., Chen F., Bao J. Plant Sci., 2008, 175:877
6
[7]. Liu B., Bian H.K., Bao J.K. Cancer Lett., 2010, 287:1
7
[8]. Kaur A., Singh J., Kamboj S.S., Sexana A.K., Pandita R.M., Shamnugavel M. Phytochemistry., 2005, 66:1933
8
[9]. Goldstein I.J., Hughes R.C., Monsigny M., Osawa T., Sharon N. Nature, 1980, 285:66
9
[10]. Warrier P.K., Nambiar V.P.K., Ramankutty C. Orient Longman publication, Madras, 1994, 2:251
10
[11]. Konozy E.H.E., Bernardes E.S., Rosa C., Faca V., Greene L.J., Ward R.J. Archiv. Biochem. Biophys., 2003, 410:222
11
[12]. Banerjee S., Chaki S., Bhowal J., Chatterjee B.P. Archiv. Biochem. Biophys., 2004, 421:125
12
[13]. Suseelan K.N., Mitra R., Pandey R., Sainis K.B., Krishna T.G. Archiv. Biochem. Biophys., 2002, 407:241
13
[14]. Gaidamashvili M., Ohizumi Y., Iijima S., Takayama T., Ogawa T., Muramoto K. J. Biol. Chem., 2004, 279:26028
14
[15]. Kaur M., Singh K., Rup P.J., Kamboj S.S., Saxena A.K., Sharma M., Bhagat M., Sood S.K., Sing J. J. Biochem. Mol. Biol., 2006, 39:432
15
ORIGINAL_ARTICLE
Efficient and green synthesis of trisubstituted imidazoles by magnetically nanocatalyst and microwave assisted
Fe3O4 magnetic nanoparticles (Fe3O4 MNPs) were prepared and used as an eco-friendly, reusable, low-cost and efficient catalyst for the synthesis of 2,4,5-trisubstituted imidazoles via three-component reaction of aromatic aldehydes with benzil and ammonium acetate under low power microwave irradiation and solvent-free condition. This one-pot procedure is very simple with good to excellent yields. Easy separation of Fe3O4 MNPs from the reaction mixture by an external magnet and the reusability of the catalyst are the considerable points of the reaction.
https://www.ajgreenchem.com/article_82505_046b97f93bb195d078bb34a494b4bbf4.pdf
2019-10-01
525
535
10.33945/SAMI/AJGC/2019.4.9
Imidazole
Benzil
Microwave irradiation
Green synthesis
Magnetic nanoparticles
Hamid Reza
Mardani
hamidreza.inorg@yahoo.com
1
Department of Chemistry, Payame Noor University (PNU), PO BOX 19395-3697 Tehran, Iran
LEAD_AUTHOR
Mehdi
Forouzani
mehdifrouzani@yahoo.com
2
Department of Chemistry, Payame Noor University (PNU), PO BOX 19395-3697 Tehran, Iran
AUTHOR
Rasoul
Emami
rasoolemami@yahoo.com
3
Department of Chemistry, Payame Noor University (PNU), PO BOX 19395-3697 Tehran, Iran
AUTHOR
[1]. Lombardino J.G., Wiseman E.H. J. Med. Chem., 1974, 17:1182
1
[2]. Lindberg P., Nordberg P., Alminger T., Brandstorm A., Wallmark B. J. Med. Chem., 1986, 29:1327
2
[3]. Pagano M.A., Andrzejewska M., Ruzzene M. J. Med. Chem., 2004, 47:6239
3
[4]. Lee J.C., Laydon J.T., McDonnell P.C., Gallagher T.F., Kumar S., Green D., McNulty D., Blumenthal M.J., Keys J.R., Landvatter S.W., Strickler J.E., McLaughlin M.M., Siemens I.R., Fisher S.M., Livi G.P., White J.R., Adams J.L., Young P.R. Nature, 1994, 372:739
4
[5]. Heeres J., Backx L.J.J., Mostmans J.H., Vancustem J. J. Med. Chem., 1979, 22:1003
5
[6]. Wasserscheid P., Keim W. Angew. Chem. Int. Ed. Eng., 2000, 39:3772
6
[7]. Bourissou D., Guerret O., Gabbai F.P., Bertrand G. Chem. Rev., 2000, 100:39
7
[8]. Mukherjee A., Kumar S., Seth M., Bhaduri A.P. Ind. J. Chem. B, 1989, 28:391
8
[9]. Ayhan-Kilcigil G., Altanlar N. Turk. J. Chem., 2006, 30:223
9
[10] . Hadizadeh F.H., Hosseinzadeh V., Shariaty M., Kazemi S.J. Pharm. Res., 2008, 7:29
10
[11]. Shingalapur R.V., Hosamani K.M., Keri R.S. Eur. J. Med. Chem., 2009, 44:4244
11
[12]. Ozkay Y., Işıkdağ I., Incesu Z., Akalin G. Eur. J. Med. Chem., 2010, 45:3320
12
[13]. Tonelli M., Simone M., Tasso B., Novelli F., Biodo V. Bioorg. Med. Chem., 2010, 18:2937
13
[14]. Bhandari K., Srinivas N., Marrapu V.K., Verma A., Srivastava S.N., Gupta S. Bioorg. Med. Chem. Lett., 2010, 20:291
14
[15]. Srinivas N., Plane S., Gupta N.S., Bhandari K. Bioorg. Med. Chem. Lett., 2009, 19:324
15
[16] . Wolkenberg S.E., Wisnoski D.D., Leister W.H., Wang Y., Zhao Z., Lindsley C.W. Org. Lett., 2004, 6:1453
16
[17]. Shaabani A., Rahmati A. J. Mol. Catal. A, 2006, 249:246
17
[18] . Kidwai M., Mothsra P., Bansal V., Somvanshi R.K., Ethayathulla A.S., Dey S., Singh T.P. J. Mol. Catal. A, 2007, 265:177
18
[19] . Khosropour A.R. Ultrason. Sonochem., 2008, 15:659
19
[20] . Samai S., Nandi G.C., Singh P., Singh M.S. Tetrahedron, 2009, 65:10155
20
[21] . Teimouri A., Najafi Chermahini A.R. J. Mol. Catal. A, 2011, 346:39
21
[22] . Sivakumar K., Kathirvel A., Lalitha A. Tetrahedron Lett., 2010, 51:3018
22
[23] . Xia M., Lu Y.D. J. Mol. Catal. A, 2007, 265:205
23
[24] . Chary M.V., Keerthysri N.C., Vupallapati S.V.N.,Srinivasu V.N., Lingaiah N., Kantevari S. Catal. Commun., 2013, 2008:9
24
[25] . Zang H., Su Q., Mo Y., Cheng B.W., Jun S. Ultrason. Sonochem., 2010, 17:749
25
[26] . Murthy S.N., Madhav B., Nageswar Y.V.D. Tetrahedron Lett., 2010, 51:5252
26
[27]. Maleki, A., Alirezvani, J. Chil. Chem. Soc., 2016, 61, 3 Nº
27
[28]. H. Naeimi, D. Aghaseyedkarimi. New J. Chem., 2015, 39:9415
28
[29]. Karami B., Hoseini S.J., Eskandari K., Ghasemi A., Nasrabadi H. Catal. Sci. Technol., 2012, 2:331
29
[30] . Caddick S. Tetrahedron Lett., 1995, 51:10403
30
[31]. Usyatinsky A.Y., Khmelnitsky Y.L. Tetrahedron Lett., 2000, 41:5031
31
[32]. Balalaie S., Hashemi M.M., Akhbari M. Tetrahedron Lett., 2003, 44:1709
32
[33] . Kang Y.S., Rishbud S., Rabolt J.F., Stroeve P. Chem. Mater., 1996, 8:2209
33
[34]. Sangshetti J.N., Kokare N.D., Kothakar S.A., Shinde D.B. Mont. Fur. Chem., 2008, 139:125
34
[35]. Abd El Aleem M., El-Remaily A.A. Tetrahedron, 2014, 70:2971
35
[36]. Mardani H.R., Ziari M. Res. Chem. Int., 2018, 44:6605
36
ORIGINAL_ARTICLE
Application of modified sawdust for solid phase extraction, preconcentration and determination of trace lead in water samples
A new sorbent was provided and exerted for separation and preconcentration of Pb (II) before the determination of lead ions by flame atomic absorption spectrometry. The normative studies on extraction, separation and preconcetration of Pb (II) were represented in the present work. This novel method was based on new sorbent by adding diethylenetriamine to sawdust and increasing incidence exterior. The effect of different parameters were studied; such as pH, ligand concentration and sample volume, type and volume of eluent and ligand effect. The optimum pH and preconcentration factor and limit of detection for Pb (II) were 4, 100 and 0.48 µg/L, respectively. Furthermore, in this approach calibration curve was linear in the range of 0.05-100 mg mL-1 with R2 = 0.995. The vertical and horizontal confines of calibration diagrams in 500 mL solution were calculated about 0-0.5 mg L-1 and 0-0.6. The results of applying the present method to determinate the separated lead ions in water samples were prosperous and harmonious. Precision of the method was investigated by comparing them with observations from previous similar researches.
https://www.ajgreenchem.com/article_83226_5c92d243ac63d0e38cded247b547ddd6.pdf
2019-10-01
536
549
10.33945/SAMI/AJGC/2019.4.10
Preconcentration
Pb (II)
Sawdust
diethylenetriamin
Solid phase extraction
Rashin
Andayesh
rashinandayesh@gmail.com
1
Department Of Chemistry, Ahvaz Science and Research Branch, Islamic Azad University, Ahvaz, Iran
LEAD_AUTHOR
Shahla
Elhami
shahla.elhamichemist@yahoo.com
2
Department Of Chemistry, Ahvaz Science and Research Branch, Islamic Azad University, Ahvaz, Iran
AUTHOR
[1]. Castro R.S.D., Caetano L., Ferreira G., Padilha P.M., Saeki M.J., Zara L.F., Martines M.A.U. Ind. Eng. Chem. Res., 2011, 50:3446
1
[2]. Dabas T., Saçmac S., Ülgen A., Kartal S. Food Chem., 2015, 174:594
2
[3]. Dabas T., Ülgen A., Kartal S. J. Ind. Eng. Chem., 2015, 28:316
3
[4]. Hossein Baki M., Shemirani F., Khani R. J. Food. Sci., 2013, 78:797
4
[5]. Khalid N.R.S., Ahmad S. Sep. Sci. Technol., 2005, 2427:43
5
[6]. Haman DJ.B.Z., Proceedings of the 10th International Conference on Environmental Science and Technology, Kos Island, Greece. 2007; p 246
6
[7]. Ebrahimzadeh H., Behbahani M. Arab J. Chem., 2013, 10:2499
7
[8]. Hossien-poor-Zaryabi M., Chamsaz M., Heidari T., Arbab Zavar M.H., Behbahani M. Food Anal. Method., 2014, 352:359
8
[9]. Benzo Z., Velosa M. J. Food Sci., 2006, 222:4
9
[10]. Behbahani M., Babapour M., Amini M.M., Sadeghi O., Bagheri A., Salarian M., Rafiee B. Am. J. Anal. Chem., 2014, 90:98
10
[11]. Divrikli U.K.A., Soylak M., Elci L. J. Hazard. Mater., 2007, 459:64
11
[12]. Liu Y.C.X., Guoa Y., Menga S. J. Hazard. Mater. B, 2006, 389:94
12
[13]. Behbahani M., Najafi M., Amini M.M., Sadeghi O., Bagheri A., Ghareh Hassanlou P. J. Ind. Eng. Chem., 2014, 2248:2255
13
[14]. Behbahani M., Abolhasani J., Amini M.M., Sadeghi O., Omidi F., Bagheri A., Food Chem, 2015, 1207:1212
14
[15]. Behbahani M., Bide Y., Salarian M., Niknezhad M., Bagheri S., Bagheri A. Food Chem., 2014, 14:19
15
[16]. Behbahani M., Amini M.M., Esrafili A., Farzadkia M., Bagheri A. Food Chem., 2015, 14:19
16
[17]. Dasbas T.S., Çankaya N., Soykan C. Food Chem., 2016, 68:73
17
[18]. Komjarova I.B.R. Anal. Chim. Acta., 2006, 221:8
18
[19]. Melek E.T.M., Soylak M. Anal. Chim. Acta., 2006, 578:213
19
[20]. Bermejo-Barrera P., Nancy M.A., Cristina D.L., Adela B.B. Microchim. Acta., 2003, 101:8
20
[21]. Mendli D. J. Food Sci., 2012, 181:6
21
[22]. Marahel F., Shokrollahi G., Montazerozohori M., Davoodi S. Chemosphere, 2009, 583:9
22
[23]. Pyrzynska K. TrAC Trends Anal. Chem., 2010, 718:27
23
[24]. Kaur A.G.U. J. Mater. Chem., 2009, 8279:89
24
[25]. Sari A.D.U., Tuzen M. Chem. Eng. J., 2011, 155:61
25
[26]. Rafatullaha M.S.O., Hashima R., Ahmad A. J. Hazard. Mater., 2009, 969:77
26
[27]. Vania M.M.R., Villanueva R.A.C., Garnica-Romo M.G., MartInez-Flores H.E. J. Food Sci., 2012, 71:10
27
[28]. Kaczala F.M.M., Hogland W. Biores. Technol., 2009, 235:43
28
[29]. Hao L., Liu Q. Li X., Du Z., Wang P. RSC Advances, 2014,4:49569
29
[30]. Shi B., Li G., Wang D., Feng C., Tang H. J. Hazard. Mater., 2007, 143:567
30
[31]. Wang H., Yuan X., Zeng G., Peng L., Liao K., Peng L., Xiao Z. Environ. Sci. Pollut Res., 2014, 21:11552
31
[32]. Sabermahani F., Bahrami H. Arab J. Chem., 2012, 9:1700
32
[33]. Tunceli A., Turker R. Talanta, 2002, 1199:1204
33
[34]. Gouda A.A., Al-Ghannam Gouda S.M. Food Chem., 2016, 202:409
34
[35]. Feist B., Mikula B. Food Chem., 2014, 147:302
35
[36]. Burham N., Azeem S.A., El-Shahat M.F. Cent. Eur. J. Chem., 2009, 945:54
36
[37]. Tewari P.K., Singh A.K. Fresenius J. Anal. Chem., 2000, 562:567
37
[38]. Ramesh A., Mohan K.R., Seshaiah K. Talanta, 2002, 243:252
38
[39]. Tuzen M.S.K., Soylak M. J. Hazard. Mater., 2008, 632:9
39
[40]. Saracoglu S., Soylak M., Elci L. J. Anal. Chem., 2003, 1127:31
40
[41]. Narin I., Soylak M., Kayakirilmaz K., Elci L. J. Anal. Lett., 2003, 641:658
41